TAILIEUCHUNG - Báo cáo " The effect of cobalt substitution on structure and magnetic properties of nickel ferrite "

A series of cobalt doped nickel ferrite with composition of Ni1-XCoXFe2O4 with x ranges from to (in steps of ) was prepared by using co-precipitation method and subsequently sintered, annealed at 6000C for 3h. The influence of the Co content on the crystal lattice parameter, the stretching vibration and the magnetization of specimens were subsequently studied. XRD and FTIR were used to investigate structure and composition variations of the samples. All samples were found to have a cubic spinel structure. . | VNU Journal of Science Mathematics - Physics 25 2009 153-159 The effect of cobalt substitution on structure and magnetic properties of nickel ferrite Nguyen Khanh Dung1 Nguyen Hoang Tuan2 1 Industry University Ho Chi Minh City 12 Nguyen Van Bao Ward 4 Go Vap District Hochiminh city Vietnam 2Can Tho University 3-2 Street Can Tho city Vietnam Received 15 August 2009 Abstract. A series of cobalt doped nickel ferrite with composition of Ni1-XCoxFe2O4 with x ranges from to in steps of was prepared by using co-precipitation method and subsequently sintered annealed at 6000C for 3h. The influence of the Co content on the crystal lattice parameter the stretching vibration and the magnetization of specimens were subsequently studied. XRD and FTIR were used to investigate structure and composition variations of the samples. All samples were found to have a cubic spinel structure. TEM was used to study morphological variations. The results indicate that the average particle sizes are between 29 35 nm. B-H hysteresis measurement was carried out at room temperature under field of 5 kOe and this measurement with the increase of Co2 concentration yields the monotonic increase of saturation magnetization MS and coercive field HC . Ferrites with such behavior are important for magnetic recording media microwave applications environment and medical biology 1-3 . In view of this we have studied the various properties of Co doped Ni ferrite. 1. Introduction NiFe2O4 has cubic inverse spinel structure with Ni2 ions occupy octahedral B - site and Fe3 ions occupy both tetrahedral A - sites and octahedral B - sites 4 . Nickel ferrite has been prepared by standard ceramic route. That are particle size micrometer low saturation magnetization and low coercivity. To our knowledge the systematic investigation of the magnetic and electrical properties of Ni1-XCoX Fe2O4 with x varied from 0 to in steps of has not been reported so far. Further Ni-Co ferrite shows the good .

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