TAILIEUCHUNG - Crystalline structure properties of bleached and unbleached wheat straw (Triticum aestivum L.) soda oxygen pulp

In this study, the crystallinity index and crystallite size of wheat straw powder, soda-oxygen pulp and soda oxygen pulp bleached with hypochlorite (H) and hypochlorite and peroxide (HP) sequences were determined using an x-ray diffractometer method. | Turk J Agric For 26 (2002) 247-252 © TÜB‹TAK Crystalline Structure Properties of Bleached and Unbleached Wheat Straw (Triticum Aestivum L.) Soda-Oxygen Pulp Esat GÜMÜfiKAYA, Mustafa USTA Karadeniz Technical University, Faculty of Forestry, Department of Pulp and Paper, 61080, Trabzon - TURKEY Received: Abstract: In this study, the crystallinity index and crystallite size of wheat straw powder, soda-oxygen pulp and soda oxygen pulp bleached with hypochlorite (H) and hypochlorite and peroxide (HP) sequences were determined using an x-ray diffractometer method. The crystallinity indexes of these pulp samples were found to be , , and , respectively. The crystallite sizes of these pulp samples were also determined and were nm, nm, nm and nm, respectively. On the other hand, the crystallinity index and crystallite size of holocellulose, cellulose and alpha-cellulose in wheat straw were then found to be , and , and nm, nm and nm, respectively. Consequently, the crystallinity index and crystallite size in pulp increase with respect to the removal of the lignin and hemicelluloses in pulp. However, the results obtained are not consistent, because the chemical agents used in the removal of the lignin and hemicelluloses may cause hydrolysis and swelling of the cellulose with a contaminant reduction in crystallinity. Key Words: Cellulose, crystallinity index, crystallite size, pulp, wheat straw, x-ray Bu¤day Sap› (Triticum Aestivum L.) Soda-Oksijen Ka¤›t Hamurunun Kristal Yap› Özellikleri Özet: Bu¤day sap› (Triticum aestivum L.) , soda-oksijen ka¤›t hamuru, hipoklorit (H) ve peroksitle (HP) kademeli a¤art›lm›fl ka¤›t hamurlar›n›n kristallik dereceleri ve kristallit genifllikleri x-›fl›n› difraktometre yöntemi kullan›larak belirlenmifltir. Bu örneklerin kristallik dereceleri s›ras›yla %, %, % ve % olarak tespit edilmifltir. Bu örneklerin kristalit genifllikleri ise yine .

• Nông nghiệp
• Crystallinity index
• Crystallite size
• Wheat straw
• X ray diffractometer method
• Soda oxygen pulp
• Acacia pulp
• Structural characteristics
• Vietnamese acacia pulp
• Investigation of the structural charateristics
• Carbohydrate Polymers
• Microcrystalline cellulose
• Surface modification
• Degradation mechanism