TAILIEUCHUNG - Magnetic Material Engineering - Chapter 6: Applications in Medical and Biology

Normally, any ferromagnetic or ferrimagnetic material undergoes a transition to a paramagnetic state above its Curie temperature. Superparamagnetism is different from this standard transition since it occurs below the Curie temperature of the material. Superparamagnetism occurs in nanoparticles which are single domain. This is possible when their diameter is below 3–50 nm, depending on the materials. In this condition, it is considered that the magnetization of the nanoparticles is a single giant magnetic moment, sum of all the individual magnetic moments carried by the atoms of the nanoparticle | Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Magnetic Material Engineering Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Magnetic nanoparticles Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Magnetic nanoparticles Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Magnetic nanoparticles Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Magnetic nanoparticles Materials: Fe, Co, Ni, Gd Spins of unfilled d-bands spontaneously align parallel inside a domain below a critical temperature TC (Curie) Laws: B = H +4 H M = H : Susceptibility Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Magnetic nanoparticles Hard Magnets: HC and Mrs have high values Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Superparamagnetism - a size effect Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Superparamagnetism - a size effect Superparamagnetism: • high saturation magnetisation MS • no remanence MR = 0 Magnetic Material Engineering Chapter 6: Applications in Medical and Biology Superparamagnetism The Néel relaxation in the absence of magnetic field Normally, any ferromagnetic or ferrimagnetic material undergoes a transition to a paramagnetic state above its Curie temperature. Superparamagnetism is different from this standard transition since it occurs below the Curie temperature of the material. Superparamagnetism occurs in nanoparticles which are single domain. This is possible when their diameter is below 3–50 nm, depending on the materials. In this condition, it is considered that the magnetization of the nanoparticles is a single giant magnetic moment, sum of all the individual magnetic moments carried by the atoms of the nanoparticle. Magnetic Material Engineering .

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