TAILIEUCHUNG - Effective role of CaO/P2O5 ratio on SiO2-CaO-P2O5 glass system

In the present work, the effect of the CaO/P2O5 ratio on the composition of sol-gel synthesized 58SiO2-(19 x)P2O5–(23 + x)CaO (x = 0, 5, 10 and 15 mol%) glass samples was studied. Further, the effect of NBO/BO ratio on hydroxy carbonated apatite layer (HCA) forming ability based on dissolution behavior in simulated body fluid (SBF) solution was also investigated. CaO/P2O5 ratios of synthesized glass samples were , 2, , and , respectively. NBO/BO ratios were obtained using Raman spectroscopic analysis as , , , and , respectively. All samples were soaked in the SBF solution for 7 days. The calculated weight losses of these samples were 58%, 64%, 83%, and 89% for corresponding NBO/BO ratios. The increase in CaO/P2O5 ratio increases the NBO/BO ratios. However, the increase in NBO/BO ratio increases HCA forming ability of SBF treated samples. The HCA crystalline layer formation was confirmed through X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), Raman and Infrared spectroscopic analysis. Higher CaO/P2O5 ratio favors the increase in HCA formation for SBF treated calcium phospho silicate glasses. | Effective role of CaO/P2O5 ratio on SiO2-CaO-P2O5 glass system

• Hoá học
• SBF solution
• HCA layer
• Effective role of CaO
• P2O5 ratio
• SiO2 CaO P2O5 glass system