TAILIEUCHUNG - Ebook Organic chemistry (6th edition): Part 2

(BQ) Part 2 book "Organic chemistry" has contents: Functional derivatives of carboxylic acids, enolate anions and enamines; benzene and the concept of aromaticity; reactions of benzene and its derivatives; catalytic carbon carbon bond formation; carbohydrates,.and other contents. | Outline Structure and Nomenclature Acidity of Amides, Imides, and Sulfonamides Chapter 18 Characteristic Reactions Functional Derivatives of Carboxylic Acids Reaction with Water: Hydrolysis Reaction with Alcohols Reaction of Acid Chlorides with Salts of Carboxylic Acids Interconversion of Functional Derivatives Reactions with Organometallic Compounds Reactions with Ammonia and Amines Reduction Colored scanning electron micrograph of Penicillium s. fungus. The stalklike objects are condiophores to which are attached numerous round condia. The condia are the fruiting bodies of the fungus. Inset: a model of amoxicillin. See Chemical Connections: “The Penicillins and Cephalosporins: b-Lactam Antibiotics.” © SCIMAT/Science Source/Photo Researchers, Inc. I n this chapter, we study five classes of organic compounds, each related to the carboxyl group: acid halides, acid anhydrides, esters, amides, and nitriles. Under the general formula of each functional group is an illustration to show you how the group is formally related to a carboxylic acid. Formal loss of !OH from a carboxyl group and H! from H!Cl, for example, gives an acid chloride. Similarly, loss of !OH from a carboxyl group and H! from ammonia gives an amide. For illustrative purposes, we show each of these reactions as a formal loss of water. However, as we will see in this chapter, some actual mechanisms do not involve a step in which an H2O molecule is lost. O O O RCCl RCOCR9 RCOR9 RCNH2 RC # N An acid chloride An acid anhydride An ester An amide A nitrile 2H2O O RC!OH Online homework for this chapter may be assigned in OWL for Organic Chemistry. 2H2O O H!Cl O O 2H2O O RC ! OH H ! OCR9 O RC ! OH H ! OR9 2H2O O RC ! OH H ! NH2 2H2O HO H RC " N The enol of an amide 680 Copyright 2010 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights,

• Hoá học
• Organic chemistry
• Functional derivatives
• Carboxylic acids
• Enolate anions
• The concept of aromaticity
• Reactions of benzene
• Catalytic carbon
• In this workbook
• experiments are elaborated using small scale glassware and equipments from a Small Lab Kit
• developed at the Department of Chemistry
• Faculty of Science
• Chulalongkorn University in Thailand
• This Small Lab Kit was created as a result of the research project entitled “Chemistry Laboratory Based on Chemical Safety and Pollution Minimization” sponsored by Thai Research Fund (RDG 3 07 2543)
• One of the outcomes of this project is the organic laboratory book entitled “Organic Chemistry Laboratory Based on Chemical Safety and Pollution Minimization” written in Thai by professors from 7 universities in this project
• They compiled
• adjusted and tested the experiments taken from several traditional organic chemistry laboratory books using the prototype of Small Lab Kit
• Currently
• some selected experiments from this Thai organic chemistry laboratory text have further been modified
• rewritten and edited in English as appeared in this workbook
• Some experiments ar
• Ebook Organic chemistry
• Nucleophilic substitution
• Determining organic structures
• nucleophilic addition
• Organic structures
• Electrophilic aromatic substitution
• Principles of organic chemistry
• Methods of organic chemistry
• The methane series
• The acetylene series
• Polybasic acids
• High school
• University entrance exam
• Teaching organic chemistry
• Organic chemistry exam question
• Interdisciplinary science
• Advanced practical organic chemistry
• Functional groups
• Organic synthesis reagents
• The structure
• Reactions of organic names
• Fundamentals of organic chemistry
• Carbonyl alpha substitution reactions
• Condensation reactions
• Structure determination
• The organic chemistry
• Organic chemistry principles in context
• Starch to the principles
• The structures of organic molecules
• Mass spectrometers
• Infrared spectrometers
• Nuclear magnetic resonance spectrometers
• Modern physical organic chemistry
• Strain and stability
• Covalent binding forces
• Electronic organic materials
• Thermal pericyclic reactions
• The study of organic chemistry
• Stereochemistry and resonance
• Identification of organic compounds
• Elimination reactions
• Electrophilic addition reactions
• Electron delocalization
• Organic compounds
• Cyclic hydrocarbons
• Aromatic alcohols
• Aromatic compounds containing
• Inorganic chemistry
• A guidebook to mechanism in organic chemistry
• Aromatic systems
• Linear free energy relationships
• Symmetry controlled reactions
• Fatty acid catabolism
• The chemistry of the carbonyl group
• The industrial road toward increasing efficiency
• Lecture Organic chemistry
• Hóa học hữu cơ
• Bài giảng Hóa học hữu cơ
• Chemistry of benzene
• Derivatives of benzene
• Summary of Organic Chemistry Dotoral Thesis
• Organic Chemistry Dotoral Thesis
• Natural Products Chemistry
• Biological evaluation
• Chemistry of natural compounds
• Ideas in chemistry
• Molecular sciences
• Synthetic chemistry
• Innovative processes in organic chemistry
• Predictive tools
• Organic chemical reactions
• Electronic Structure
• Electronic configurations of atoms
• Electronic configurations
• Wave properties of electrons
• Wave interactions
• Stereochemistry of alkanes
• Alkane conformations
• Chemical reactions
• Chlorination of Methane
• Chiral carbons
• Nonmobile conformers
• Alkyl Halides