TAILIEUCHUNG - Lecture Companion site to accompany thermodynamics: An engineering approach (7/e): Chapter 16 - Yunus Çengel, Michael A. Boles

Chapter 16 - Chemical and phase equilibrium. After completing this chapter, students will be able to: Develop the equilibrium criterion for reacting systems based on the second law of thermodynamics, more specifically, the increase of entropy principle; develop a general criterion for chemical equilibrium applicable to any reacting system based on minimizing the Gibbs function for the system; define and evaluate the chemical equilibrium constant;. | Chapter 16 Chemical and Phase Equilibrium Study Guide in PowerPoint to accompany Thermodynamics: An Engineering Approach, 7th edition by Yunus A. Çengel and Michael A. Boles Consider the combustion of propane with 120 percent theoretical air. The combustion equation is Conservation of mass for each species yields: For more information and animations illustrating this topic visit the Animation Library developed by Professor S. Bhattacharjee, San Diego State University, at this link. Since the percent theoretical air is known, the N2 balance gives B. The H balance gives G. Then the C and O balances give two equations that relate the remaining three unknowns D, E, and F. Therefore, we need one more equation. To obtain this last equation relating the mole numbers of the products, we assume that the products are in chemical equilibrium. To develop the relations for chemical equilibrium, consider placing the product .

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