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The successive editions of Principles and Practice of Analytical Chemistry have kept pace with the associated developments in the subject. Significant changes encompass strengthening of the coverage of data handling, together with new material covering rapidly developing subject areas of molecular spectrometry, atomic spectrometry, and separation techniques. Answers to the self- learning problems and exercises are also included. All sections of the book have been fully reviewed and updated as appropriate. . | Page iii Principles and Practice of Analytical Chemistry Fifth Edition F.W. Fifield Kingston University and D. Kealey University of Surrey b Blackwell SciitiM Page iv 2000 by Blackwell Science Ltd Editorial Offices Osney Mead Oxford OX2 0EL 25 John Street London WC1N 2BL 23 Ainslie Place Edinburgh EH3 6AJ 350 Main Street Malden Ma 02148 5018 USA 54 University Street Carlton Victoria 3053 Australia 10 rue Casimir Delavigne 75006 Paris France Other Editorial Offices Blackwell Wissenschafts-Verlag GmbH Kurfurstendamm 57 10707 Berlin Germany Blackwell Science KK MG Kodenmacho Building 7-10 Kodenmacho Nihombashi Chuo-ku Tokyo 104 Japan The right of the Authors to be identified as the Authors of this Work has been asserted in accordance with the Copyright Designs and Patents Act 1988. All rights reserved. No part of this publication may be reproduced stored in a retrieval system or transmitted in any form or by any means electronic mechanical photocopying recording or otherwise except as permitted by the UK Copyright Designs and Patents Act 1988 without the prior permission of the publisher. First Edition published 1975 by Chapman Hall Second Edition 1983 Third Edition 1990 Fourth Edition 1995 This Edition published 2000 Set in 10 12pt Times by DP Photosetting Aylesbury Bucks Printed and bound in the United Kingdom at the University Press Cambridge The Blackwell Science logo is a trade mark of Blackwell Science Ltd registered at the United Kingdom Trade Marks Registry DISTRIBUTORS Marston Book Services Ltd PO Box 269 Abingdon OxonOX14 4YN Orders Tel 01235 465500 Fax 01235 465555