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The state-of-the-art of controlled radical polymerization (CRP) in 2011 is presented. Atom transfer radical polymerization, stable radical mediated polymerization, and degenerate transfer processes, including reversible addition fragmentation chain transfer are the most often used CRP procedures. CRP opens new avenues to novel materials from a large range of monomers. Detailed structure-reactivity relationships and mechanistic understanding not only helps attain a better controlled polymerization but enables preparation of polymers with complex architectures. Correlation of macromolecular structure with final properties of prepared materials is a prerequisite for creation of new applications and commercialization of various CRP products | Progress in Controlled Radical Polymerization Mechanisms and Techniques ACS SYMPOSIUM SERIES 1100 Progress in Controlled Radical Polymerization Mechanisms and Techniques Krzysztof Matyjaszewski Editor Carnegie Mellon University Pittsburgh Pennsylvania Brent S. Sumerlin Editor Southern Methodist University Dallas Texas Nicolay V. Tsarevsky Editor Southern Methodist University Dallas Texas Sponsored by the ACS Division of Polymer Chemistry Inc. American Chemical Society Washington DC Distributed in print by Oxford University Press .
