TAILIEUCHUNG - Ferroelectrics Characterization and Modeling Part 12

Tham khảo tài liệu 'ferroelectrics characterization and modeling part 12', kỹ thuật - công nghệ, cơ khí - chế tạo máy phục vụ nhu cầu học tập, nghiên cứu và làm việc hiệu quả | Intrinsic Interface Coupling in Ferroelectric Heterostructures and Superlattices 375 because f2 0 for a non-polar dielectric. p and q are the order parameters of the ferroelectric and dielectric consituents respectively. a1 is a temperature-dependent parameter 1 10 T-T0 6 where 10 0 is a temperarature-independent parameter. a2 0 P 0 K1 0 and K1 0 are all temperature-independent coefficients. The equilibrium states of the heterostructures correspond to the minima of F with respect to variations of p and q. These are given by solving the Euler-Lagrange equations for p and q dF I dF j 0 dp dx dp J dFI dF j 0 dq dx dq J 7 with the boundary conditions p pi _ n at x 0 q q 8a and dp p pb and 0 at x - dx dq n . q qb and - 0 at x dx 8b where pb and qb are the bulk polarization of the ferroelectric constituent A at x - and the dielectric constituent B at x respectively. For the present study of ferroelectric dielectric heterostructure of interface it turns out that the free energy F of eq. 1 can be rewritten in terms of the interface polarizations pi and qi as order parameters. This gives F as a function of pi and qi without the usual integral form. Solving eqs. 1 and 7 simultaneously with the boundary conditions . eqs. 8a and 8b imposed and integrating once the Euler-Lagrange equations becomes a2L p2 - pb2 K- p2 - pt K1 pjp J 9 and 2 2_ K2 I dq 2 2 q 2 I dx J By solving eq. 9 the polarization of the ferroelectric constituent A becomes 10 376 Ferroelectrics - Characterization and Modeling . . K. . P pb tanh J1 X - x 11 where K1 For the dielectric constituent B the solution of eq. 10 gives q qi exp K2x 12 13 with K2 a k2. 14 If P is determined xi can be obtained from eq. 11 . In eqs. 11 and 13 the magnitude of the interface polarizations Pi and qi are determined by the interface coupling parameter Ả. The total energy eq. 1 of the heterostructure can be written in terms of Pi and qi as F 3 F P3 - 3PiP2 2P3 2arLq2 i Pi qi 2. 15 The equilibrium structure can be found from ItJ

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