TAILIEUCHUNG - Chemical Oxidation

Permanganate may be applied to sites as either potassium permanganate (KMnO4) or sodium permanganate (NaMnO4). Where cost dominates over engineering factors at a site, potassium permanganate is the preferred chemical form because it is more widely available, less costly, and is available in solid form, which facilitates transport and handling. Where other factors are more important, the liquid form of sodium permangante is preferable. When choosing potassium permanganate for application at a site, be aware of three properties that can cause concern to owner, operators or state regulators. First, potassium permanganate is derived from mined potassium ores which, by their nature, typically contain salt and metal. | Chapter XIII Chemical Oxidation Contents Overview .XIII-1 Hydrogen Peroxide Fenton s Special Considerations for Chemical Oxidation Technology Effectiveness Screening Step 1 Initial Screening of Chemical Oxidation Overall Viability .XIII-15 Potential Effectiveness of Chemical Oxidation .XIII-16 Step 2 Detailed Evaluation of Chemical Oxidation Effectiveness .XIII-18 Site Characteristics That Affect Chemical Oxidation .XIII-18 Oxidant Demand Advective Dispersive Transport Constituent Characteristics That Affect Chemical Oxidation .XIII-24 Step 3 Evaluation of Chemical Oxidation Design Basis .XIII-27 Cleanup Chemical Oxidation Technology Selection .XIII-30 Design Oxidation Application Design .XIII-32 Permit Requirements and Performance Monitoring .XIII-33 Contingency Components of Chemical Oxidation Systems .XIII-34 Injection Extraction and Re-Infiltration Well Step 4 An Evaluation of the Operation and Monitoring Remedial Progress Evaluation Sampling .XIII-39 Evaluation Criteria. XIII-43 Oxidant Delivery and Permanent Contaminant Mass Reduction and Attainment of Cleanup References .XIII-46 Checklist Can Chemical Oxidation Be Used At This Site .XIII-48 May 2004 XIII-ii List of Exhibits Number Title Page XIII-1 Chemical Oxidation Primary Advantages and Disadvantages. XIII-3 XIII-2 Chemical Oxidation Technologies Comparative Matrix. XIII-5 XIII-3 Initial Screening For Chemical Oxidation Remediation Potential Effectiveness . XIII-14 XIII-4 Detailed Screening For Chemical Oxidation Remediation Potential Effectiveness. XIII-17 XIII-5 Key Parameters Used To Evaluate Chemical Oxidation Applicability. XIII-18 XIII-6 Inorganic Oxidation Processes That Consume Dissolved

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