TAILIEUCHUNG - Alkoxo and Aryloxo Derivatives of Metals Elsevier

In 1978 the book entitled “Metal Alkoxides” was It contained over one thousand references and attempted to summarize most of what was known about metal alkoxides up to that time. A striking feature was the dearth of X-ray crystal structures and so structural aspects necessarily involved speculation based on the results of molecular weight determinations, combined where possible with spectroscopic data. | ẢlkoiD and Arylnio ũ-erĩvatìvBS of Metals Alkoxo and Aryloxo Derivatives of Metals Elsevier 2001 Author . Bradley . Mehrotra . Rothwell and A. Singh ISBN 978-0-12-124140-7 Foreword Page xi 1 - Introduction Pages 1-2 2 - Homometallic Alkoxides Pages 3-181 3 - Heterometallic Alkoxides Pages 183-228 4 - X-Ray Crystal Structures of Alkoxo Metal Compounds Pages 229-382 5 - Metal Oxo-alkoxides Pages 383-443 6 - Metal Aryloxides Pages 445-669 7 - Industrial Applications Pages 671-686 Index Pages 687-704 Foreword The value of a book may well be judged by the number of times a person has to buy it for while many books once read gather dust upon a shelf those more often sought can sometimes be seldom found. Over 20 years ago I was fortunate to receive a complimentary copy of Metal Alkoxides by Bradley Mehrotra and Gaur. As one interested in alkoxide metal chemistry this proved a valuable reference for me and my research group. In fact I had to purchase two subsequent copies and probably would have purchased more were it not for the fact that the book became out of print and unavailable except through the library. Now I have received the galley proofs of the second edition entitled Alkoxo and Aryloxo Derivatives of Metals by Bradley Mehrotra Rothwell and Singh. After 20 years virtually every field of chemistry must have changed to the extent that a new edition would be appropriate. However it is unlikely that any field of chemistry save computational chemistry will have changed as much as that of the chemistry of metal alkoxides and aryloxides during the period 1978-2000. The explosion of interest in metal alkoxides has arisen primarily for two reasons. First and foremost we have witnessed the tremendous growth of materials chemistry spurred on by the discovery of high temperature superconducting oxides and by the increasingly important role of other metal oxides to technology. Metal alkoxides mixed metal alkoxides and their related complexes have played an essential

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