TAILIEUCHUNG - Ebook Organic chemistry (7th edition): Part 2 - John McMurry

(BQ) Part 2 book "Organic chemistry" has contents: Functional derivatives of carboxylic acids, enolate anions and enamines; benzene and the concept of aromaticity; reactions of benzene and its derivatives; catalytic carbon carbon bond formation; carbohydrates,.and other contents. | 600 CHAPTER 17 Alcohols and Phenols annually in the United States by fermentation of corn barley and sorghum and production is expected to double by 2012. Essentially the entire amount is used to make E85 automobile fuel a blend of 85 ethanol and 15 gasoline. Ethanol for nonbeverage use is obtained by acid-catalyzed hydration of ethylene. Approximately 110 million gallons of ethanol a year is produced in the United States for use as a solvent or as a chemical intermediate in other industrial reactions. H2C CH2 h20 h3po4 250 C CH3CH2OH Phenols occur widely throughout nature and also serve as intermediates in the industrial synthesis of products as diverse as adhesives and antiseptics. Phenol itself is a general disinfectant found in coal tar methyl salicylate is a flavoring agent found in oil of Wintergreen and the urushiols are the allergenic constituents of poison oak and poison ivy. Note that the word phenol is the name both of the specific compound hydroxybenzene and of a class of compounds. Phenol also known as carbolic acid Urushiols R different Cqg alkyl and alkenyl chains WHY THIS CHAPTER Up to this point we ve focused on developing some general ideas of organic reactivity on looking at the chemistry of hydrocarbons and on seeing some of the tools used in structural studies. With that background it s now time to begin a study of the oxygen-containing functional groups that lie at the heart of biological chemistry. We ll look at alcohols in this chapter and then move on to carbonyl compounds in Chapters 19 through 23. Naming Alcohols and Phenols Thomson Click Organic Interactive to use a web-based palette to draw structures of alcohols based on their IUPAC names. Alcohols are classified as primary 1 secondary 2 or tertiary 3 depending on the number of organic groups bonded to the hydroxyl-bearing carbon. OH I A R H H OH I Rý H R OH I R 7 r R A primary 1 alcohol A secondary 2 alcohol A tertiary 3 alcohol Naming Alcohols and Phenols 601 Simple .

• Hoá học
• Organic chemistry
• Functional derivatives
• Carboxylic acids
• Enolate anions
• The concept of aromaticity
• Reactions of benzene
• Catalytic carbon
• In this workbook
• experiments are elaborated using small scale glassware and equipments from a Small Lab Kit
• developed at the Department of Chemistry
• Faculty of Science
• Chulalongkorn University in Thailand
• This Small Lab Kit was created as a result of the research project entitled “Chemistry Laboratory Based on Chemical Safety and Pollution Minimization” sponsored by Thai Research Fund (RDG 3 07 2543)
• One of the outcomes of this project is the organic laboratory book entitled “Organic Chemistry Laboratory Based on Chemical Safety and Pollution Minimization” written in Thai by professors from 7 universities in this project
• They compiled
• adjusted and tested the experiments taken from several traditional organic chemistry laboratory books using the prototype of Small Lab Kit
• Currently
• some selected experiments from this Thai organic chemistry laboratory text have further been modified
• rewritten and edited in English as appeared in this workbook
• Some experiments ar
• Ebook Organic chemistry
• Nucleophilic substitution
• Determining organic structures
• nucleophilic addition
• Organic structures
• Electrophilic aromatic substitution
• Principles of organic chemistry
• Methods of organic chemistry
• The methane series
• The acetylene series
• Polybasic acids
• High school
• University entrance exam
• Teaching organic chemistry
• Organic chemistry exam question
• Interdisciplinary science
• Advanced practical organic chemistry
• Functional groups
• Organic synthesis reagents
• The structure
• Reactions of organic names
• Fundamentals of organic chemistry
• Carbonyl alpha substitution reactions
• Condensation reactions
• Structure determination
• The organic chemistry
• Organic chemistry principles in context
• Starch to the principles
• The structures of organic molecules
• Mass spectrometers
• Infrared spectrometers
• Nuclear magnetic resonance spectrometers
• Modern physical organic chemistry
• Strain and stability
• Covalent binding forces
• Electronic organic materials
• Thermal pericyclic reactions
• The study of organic chemistry
• Stereochemistry and resonance
• Identification of organic compounds
• Elimination reactions
• Electrophilic addition reactions
• Electron delocalization
• Organic compounds
• Cyclic hydrocarbons
• Aromatic alcohols
• Aromatic compounds containing
• Inorganic chemistry
• A guidebook to mechanism in organic chemistry
• Aromatic systems
• Linear free energy relationships
• Symmetry controlled reactions
• Fatty acid catabolism
• The chemistry of the carbonyl group
• The industrial road toward increasing efficiency
• Lecture Organic chemistry
• Hóa học hữu cơ
• Bài giảng Hóa học hữu cơ
• Chemistry of benzene
• Derivatives of benzene
• Summary of Organic Chemistry Dotoral Thesis
• Organic Chemistry Dotoral Thesis
• Natural Products Chemistry
• Biological evaluation
• Chemistry of natural compounds
• Ideas in chemistry
• Molecular sciences
• Synthetic chemistry
• Innovative processes in organic chemistry
• Predictive tools
• Organic chemical reactions
• Electronic Structure
• Electronic configurations of atoms
• Electronic configurations
• Wave properties of electrons
• Wave interactions
• Stereochemistry of alkanes
• Alkane conformations
• Chemical reactions
• Chlorination of Methane
• Chiral carbons
• Nonmobile conformers
• Alkyl Halides