TAILIEUCHUNG - Ebook Organic chemistry (8th edition): Part 2

(BQ) Part 1 book "Organic chemistry" has contents: Organometallic compounds, carboxycilic acids, enols and enolates, carbohydrates; nucleosides, nucleotides, and nucleic acids; amino acids, peptides, and proteins; lipids, amines; ethers, epoxides, and sulfides,.and other contents. | Organometallic Compounds Chapter Outline Organometallic Nomenclature 607 Carbon-Metal Bonds in Organometallic Compounds 608 Preparation of Organolithium Compounds 609 Preparation of Organomagnesium Compounds Grignard Reagents 610 Organolithium and Organomagnesium Compounds as Bronsted Bases 612 Synthesis of Alcohols Using Grignard Reagents 614 Synthesis of Alcohols Using Organoiithium Reagents 616 Synthesis of Acetylenic Alcohols 616 Retrosynthetic Analysis 617 Alkane Synthesis Using Organocopper Reagents 620 An Organozinc Reagent for Cyclopropane Synthesis 622 Carbenes and Carbenoids 623 Transition-Metal Organometallic Compounds 625 An Organometallic Compound That Occurs Naturally Coenzyme B12 627 Homogeneous Catalytic Hydrogenation 628 Olefin Metathesis 631 Ziegler-Natta Catalysis of Alkene Polymerization 634 Summary 636 Problems 639 Descriptive Passage and Interpretive Problems 14 The Heck Reaction 643 Mechanisms Formation of a Lithium Dialkylcuprate Gilman Reagent 621 Similarities Between the Mechanisms of Reaction of an Alkene with lodomethylzinc Iodide and a Peroxy Acid 624 Homogeneous Hydrogenation of Propene in the Presence of Wilkinson s Catalyst 629 Olefin Cross-Metathesis 632 Polymerization of Ethylene in the Presence of a Ziegler-Natta Catalyst 635 606 ORGANOMETALLIC COMPOUNDS ARE compounds that have a carbon-metal bond they lie at the place where organic and inorganic chemistry meet. You are already familiar with at least one organometallic compound sodium acetylide NaC CH which has an ionic bond between carbon and sodium. But just because a compound contains Steel towers support the steel cables that hold the bridge. Steel is iron to which some carbon has been added. An iron atom lies between two carbon-based rings in a ferrocene molecule. both a metal and carbon isn t enough to classify it as organometallic. Like sodium acetylide .

• Hoá học
• Organometallic compounds
• Carboxycilic acids
• Nucleic acids
• Amino acids
• Cabocylic acid derivatives
• Enols and enolates
• Chemical elements
• inorganic compounds
• molecules
• crystalline lattice
• organometallic
• Nuclear Quadrupole
• Solid State NMR Spectroscopy
• Paramagnetic Complexes
• Dynamic Systems
• NMR Spectroscopy
• range of inorganic
• physical chemistry
• state chemistry
• coordination chemistry
• bioinorganic chemistry
• The group 17 elements
• The group 18 elements
• Inorganic chemistry
• The second and third row metals
• d Block metal chemistry
• General considerations
• The transition elements
• Advanced inorganic chemistry
• The electronic structures
• Homogeneous catalytic reactions
• Transition matal complexes
• Journal of Chemistry
• Solid phase extraction
• Trace elements
• Biological systems
• Chiral Oxirans
• Miscellaneous Syntheses
• Miscellaneous reactions
• nitrogen nucleophiles
• Thermal and Photochemical
• Organic chemistry
• Chemical bonding
• Elimination reactions
• Nucleophilic substitution
• Conjugation in alkadienes and allylic systems
• Arenes and aromaticity